Head:
Associate Professor of the Department of General and Inorganic Chemistry
Structural unit: Faculty of Science.
The research is being conducted in the laboratories to develop methods for the synthesis of coordination compounds of platinum metals with sulfur-containing ligands and to study their properties.
Resources
The laboratory base allows to use the following research methods:
- Electronic absorption spectrophotometry
- IR Fourier spectroscopy
- Coherent Raman spectroscopy
Equipment fleet
- Sagu 50 Spectrophotometer (Varian)
- IRSpirit IR spectrometer (Shimadzu)
- EnSpectr R 532 RAMAN spectrometer
- Laboratory equipment for synthetic work
The laboratory team is engaged in the synthesis of coordination compounds of platinum metals.
- Develops and improves methods for obtaining new coordination compounds
- Examines the spectral characteristics of compounds
- Studies various properties of compounds, including transformations in solutions
Partners
- N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
- N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
- National Research Centre “Kurchatov Institute”
- A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
- Study of the interaction of halide compounds of platinum metals with organic ligands in solutions
- Synthesis of platinum metal coordination compounds
- Study of the spectral characteristics of the obtained compounds by a complex of physico-chemical methods
- Study of various properties and transformations, including in solutions
New coordination compounds of platinum metals (osmium, ruthenium, iridium) with organic sulfur-containing ligands (thiocarbamide, DMSO) were synthesized using the developed methods.
Dimethyl sulfoxide coordination compounds of iridium (IV) and osmium (IV) have been obtained for the first time. Their spectral characteristics, including transformations in solutions, have been studied. To obtain it, synthesis was used through the stage of formation of an intermediate labile complex of platinum metal (IV) with a solvent, for example, acetone.