Scientific seminar “Lanthanide‐based Silsesquioxane: Synthesis, Structure, and Properties”
We report here the synthesis, structure, luminescence and magnetic properties of new cage-like tetranuclear silsesquioxanes Tb3+, Eu3+, Dy3+. They present an unusual prism-like topology of cage architectures and lanthanide-characteristic emission, which makes them the first luminescent cage-like lanthanide silsesquioxanes.